Multitopic Supramolecular Detection of Chemical Warfare Agents by Fluorescent Sensors

Development of Molecularly Imprinted Polymer Sensors for Chemical Warfare Agents

o protect personnel from hazardous materials, substances must be unambiguously detected in real time. This goal is being pursued with the application of a wide range of technologies. Most chemical sensors must strike a compromise between sensitivity and selectivity to meet the real-time goal. The sensor platform described in this article is designed to eliminate any such compromise. Thus far, w...

[Decontamination of chemical warfare agents by photocatalysis].

Photocatalysis has been widely applied to solar-energy conversion and environmental purification. Photocatalyst, typically titanium dioxide (TiO(2)), produces active oxygen species under irradiation of ultraviolet light, and can decompose not only conventional pollutants but also different types of hazardous substances at mild conditions. We have recently started the study of photocatalytic dec...

Fluorescent detection of chemical warfare agents: functional group specific ratiometric chemosensors.

Indicators providing highly sensitive and functional group specific fluorescent response to diisopropyl fluorophosphate (DFP, a nerve gas (G-agent) simulant) are reported. Nonemissive indicator 2 reacts with DFP to give a cyclized compound 2+A- that shows a high emission due to its highly planar and rigid structure. Very weak emission was observed by the addition of HCl. Another indicator based...

Chemical Warfare Agents

Badges of Immobilized Enzymes: Detection of Chemical Warfare Agents

Rapid detection of chemical warfare agents (CWAs) in all of its forms including gas and liquid is of paramount importance to protect the warfighter or first responders in homeland defense. CWAs such as OPs and vesicants pose serious threats because these agents can be ingested with contaminated food or rapidly penetrate skin. We reported that polyurethane immobilized cholinesterases (acetyl and...